FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4308741337> ?p ?o ?g. }

• W4308741337 endingPage "558" @default.
• W4308741337 startingPage "549" @default.
• W4308741337 abstract "The confinement effect known as efficient strategy to enhance the heterocatalytic activity and stability, but a clear view regarding the role of encapsulated overlayers is far from convincing at present, especially, the penetration of substrates with different size. Herein, the experimental evidence about the impacts of BN overlayers on hydrogenation is obtained over [email protected]/BN model catalysts with tuned thinness, in which BN overlayers encapsuled Co particles that dispersed on the defective BN supports, fabricating by the nitridizing of ball-milled BN microplates under NH3 atmosphere. The thinness and crystallinity of BN shells was simply tuned by controlling the pyrolyzed temperature (600–900 °C). The cinnamaldehyde (CAL) selective hydrogenation is taken as probe reaction due to (1) both larger CAL and small H2 molecule involved simultaneously, (2) the middle CC and terminal CO bonds all involved. Combined with structural analysis, the results demonstrate that small H2 molecule can penetrate into the metal-cover interface through the defect sites, then inner Co core dissociate it to atomic H, and the hydrogenation mainly resulting from the spillover of H atoms which occurred on the BN surface. As a result, the thickest BN shells (∼3.4 nm) with ordered-layer-lattice significantly hindered the adsorption and activation of CAL, also the longest H spillover distance led to the lowest activity of [email protected]/BN-900. Instead, [email protected]/BN-600 with merely 2 ∼ 3 overlayers presented the most efficient and highly chemoselective hydrogenation activity. The ultrathin but turbostratic BN overlayers provide more migrating sites also shortened the H spillover distance effectively, and the more favorable CO hydrogenation was also achieved driven by the steric hindrance effect of thinner BN shells. These observations provide new insights towards understanding of confined effect on catalysis process through the accurate regulation of BN shells properties." @default.
• W4308741337 created "2022-11-15" @default.
• W4308741337 creator A5038696885 @default.
• W4308741337 creator A5049324815 @default.
• W4308741337 creator A5064240723 @default.
• W4308741337 creator A5083967189 @default.
• W4308741337 creator A5087770639 @default.
• W4308741337 date "2023-01-01" @default.
• W4308741337 modified "2023-10-16" @default.
• W4308741337 title "Effect of boron nitride overlayers on Co@BNNSs/BN-Catalyzed aqueous phase selective hydrogenation of cinnamaldehyde" @default.
• W4308741337 cites W1983669046 @default.
• W4308741337 cites W2002809931 @default.
• W4308741337 cites W2048585881 @default.
• W4308741337 cites W2052026247 @default.
• W4308741337 cites W2059584572 @default.
• W4308741337 cites W2065679720 @default.
• W4308741337 cites W2146799566 @default.
• W4308741337 cites W2177026884 @default.
• W4308741337 cites W2260428478 @default.
• W4308741337 cites W2317390902 @default.
• W4308741337 cites W2332893944 @default.
• W4308741337 cites W2344974816 @default.
• W4308741337 cites W2502893771 @default.
• W4308741337 cites W2506751337 @default.
• W4308741337 cites W2509715085 @default.
• W4308741337 cites W2532458833 @default.
• W4308741337 cites W2539737936 @default.
• W4308741337 cites W2557521583 @default.
• W4308741337 cites W2566680603 @default.
• W4308741337 cites W2596655946 @default.
• W4308741337 cites W2606247604 @default.
• W4308741337 cites W2622779363 @default.
• W4308741337 cites W2624379335 @default.
• W4308741337 cites W2742906609 @default.
• W4308741337 cites W2780975837 @default.
• W4308741337 cites W2782814121 @default.
• W4308741337 cites W2784850000 @default.
• W4308741337 cites W2799280451 @default.
• W4308741337 cites W2809214673 @default.
• W4308741337 cites W2810773326 @default.
• W4308741337 cites W2887217471 @default.
• W4308741337 cites W2899756927 @default.
• W4308741337 cites W2953477990 @default.
• W4308741337 cites W3001728099 @default.
• W4308741337 cites W3003370668 @default.
• W4308741337 cites W3003686937 @default.
• W4308741337 cites W3131303146 @default.
• W4308741337 cites W3158666886 @default.
• W4308741337 cites W3167503671 @default.
• W4308741337 cites W3179953942 @default.
• W4308741337 cites W4224212721 @default.
• W4308741337 cites W4280521098 @default.
• W4308741337 cites W4280544293 @default.
• W4308741337 doi "https://doi.org/10.1016/j.jcis.2022.10.117" @default.
• W4308741337 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36334490" @default.
• W4308741337 hasPublicationYear "2023" @default.
• W4308741337 type Work @default.
• W4308741337 citedByCount "3" @default.
• W4308741337 countsByYear W43087413372023 @default.
• W4308741337 crossrefType "journal-article" @default.
• W4308741337 hasAuthorship W4308741337A5038696885 @default.
• W4308741337 hasAuthorship W4308741337A5049324815 @default.
• W4308741337 hasAuthorship W4308741337A5064240723 @default.
• W4308741337 hasAuthorship W4308741337A5083967189 @default.
• W4308741337 hasAuthorship W4308741337A5087770639 @default.
• W4308741337 hasConcept C127413603 @default.
• W4308741337 hasConcept C147789679 @default.
• W4308741337 hasConcept C150394285 @default.
• W4308741337 hasConcept C155672457 @default.
• W4308741337 hasConcept C159985019 @default.
• W4308741337 hasConcept C161790260 @default.
• W4308741337 hasConcept C171250308 @default.
• W4308741337 hasConcept C178790620 @default.
• W4308741337 hasConcept C185592680 @default.
• W4308741337 hasConcept C192562407 @default.
• W4308741337 hasConcept C2777435628 @default.
• W4308741337 hasConcept C2780243435 @default.
• W4308741337 hasConcept C42360764 @default.
• W4308741337 hasConcept C46275449 @default.
• W4308741337 hasConcept C8010536 @default.
• W4308741337 hasConceptScore W4308741337C127413603 @default.
• W4308741337 hasConceptScore W4308741337C147789679 @default.
• W4308741337 hasConceptScore W4308741337C150394285 @default.
• W4308741337 hasConceptScore W4308741337C155672457 @default.
• W4308741337 hasConceptScore W4308741337C159985019 @default.
• W4308741337 hasConceptScore W4308741337C161790260 @default.
• W4308741337 hasConceptScore W4308741337C171250308 @default.
• W4308741337 hasConceptScore W4308741337C178790620 @default.
• W4308741337 hasConceptScore W4308741337C185592680 @default.
• W4308741337 hasConceptScore W4308741337C192562407 @default.
• W4308741337 hasConceptScore W4308741337C2777435628 @default.
• W4308741337 hasConceptScore W4308741337C2780243435 @default.
• W4308741337 hasConceptScore W4308741337C42360764 @default.
• W4308741337 hasConceptScore W4308741337C46275449 @default.
• W4308741337 hasConceptScore W4308741337C8010536 @default.
• W4308741337 hasFunder F4320321001 @default.
• W4308741337 hasFunder F4320322666 @default.
• W4308741337 hasLocation W43087413371 @default.

• next