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- W4386272110 abstract "Ni-based catalysts have been widely studied in the hydrogenation of CO2 to CH4 , but selective and efficient synthesis of higher alcohols (C2+ OH) from CO2 hydrogenation over Ni-based catalyst is still challenging due to successive hydrogenation of C1 intermediates leading to methanation. Herein, we report an unprecedented synthesis of C2+ OH from CO2 hydrogenation over K-modified Ni-Zn bimetal catalyst with promising activity and selectivity. Systematic experiments (including XRD, in situ spectroscopic characterization) and computational studies reveal the in situ generation of an active K-modified Ni-Zn carbide (K-Ni3 Zn1 C0.7 ) by carburization of Zn-incorporated Ni0 , which can significantly enhance CO2 adsorption and the surface coverage of alkyl intermediates, and boost the C-C coupling to C2+ OH rather than conventional CH4 . This work opens a new catalytic avenue toward CO2 hydrogenation to C2+ OH, and also provides an insightful example for the rational design of selective and efficient Ni-based catalysts for CO2 hydrogenation to multiple carbon products." @default.
- W4386272110 created "2023-08-31" @default.
- W4386272110 creator A5028720605 @default.
- W4386272110 creator A5040679757 @default.
- W4386272110 creator A5047667763 @default.
- W4386272110 creator A5054352845 @default.
- W4386272110 creator A5065936183 @default.
- W4386272110 creator A5081093007 @default.
- W4386272110 date "2023-09-07" @default.
- W4386272110 modified "2023-10-11" @default.
- W4386272110 title "In‐Situ‐Formed Potassium‐Modified Nickel‐Zinc Carbide Boosts Production of Higher Alcohols beyond CH4 in CO2 Hydrogenation" @default.
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- W4386272110 doi "https://doi.org/10.1002/anie.202311335" @default.
- W4386272110 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37646093" @default.
- W4386272110 hasPublicationYear "2023" @default.
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