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- W754403829 abstract "Monodisperse cobalt (Co) nanoparticles (NPs) were synthesized and stabilized against oxidation via reductive annealing at 600 °C. The stable Co NPs are active for catalyzing the oxygen evolution reaction (OER) in 0.1 M KOH, producing a current density of 10 mA/cm(2) at an overpotential of 0.39 V (1.62 V vs RHE, no iR-correction). Their catalysis is superior to the commercial Ir catalyst in both activity and stability. These Co NPs are also assembled into a monolayer array on the working electrode, allowing the detailed study of their intrinsic OER activity. The Co NPs in the monolayer array show 15 times higher turnover frequency (2.13 s(-1)) and mass activity (1949 A/g) than the NPs deposited on conventional carbon black (0.14 s(-1) and 126 A/g, respectively) at an overpotential of 0.4 V. These stable Co NPs are a promising new class of noble-metal-free catalyst for water splitting." @default.
- W754403829 created "2016-06-24" @default.
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- W754403829 date "2015-06-01" @default.
- W754403829 modified "2023-10-18" @default.
- W754403829 title "Stable Cobalt Nanoparticles and Their Monolayer Array as an Efficient Electrocatalyst for Oxygen Evolution Reaction" @default.
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- W754403829 doi "https://doi.org/10.1021/jacs.5b04142" @default.
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