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- W86089199 abstract "The possibility of stereodirected synthesis of 1-[(2 E )-hept-2-en-1-yl]piperidine and 1-[(2 Z )-hept-2-en-1-yl]piperidine based on cross-coupling of isomers of 1-(3-chloroprop-2-en-1-yl)piperidine with butylmagnesiumchloride was researched. The cross-coupling of individual (2 E )and (2 Z )-1-(3-chloroprop-2-en-1-yl)piperidines with butylmagnesiumchloride catalyzed by Fe(acac) 3 in mixture of tetrahydrofuran and N-methylpyrrolidone occurs with formation of corresponding isomers of 1-(hept-2-en-1-yl)-piperidine in high yield (84 and 81%) and stereoselectivity (99 and 95%). The initial stereochemically pure (2 E )and (2 Z )-1-(3-chloroprop-2-en-1-yl)piperidines were synthesized by allylic amination of individual isomers of 1,3-dichloropropene by piperidine." @default.
- W86089199 created "2016-06-24" @default.
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- W86089199 date "2013-01-01" @default.
- W86089199 modified "2023-09-23" @default.
- W86089199 title "Кросс-сочетание (2 e)и (2 z)-1-(3-хлорпроп-2-ен-1-ил)-пиперидинов с бутилмагнийхлоридом" @default.
- W86089199 hasPublicationYear "2013" @default.
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