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- W86229331 abstract "For the investigation of the electronic character of catalytic reactions, it has been found fruitful to study not only the catalytic action of metals and semiconductors of known electron state distribution, but also the changes of this distribution by illumination during catalysis. The Warburg-Barcroft technique of biochemistry has proved to be very suitable for this purpose. It could be shown in a semiquantitative way that promotion of electrons enhances acceptor reactions, that electron traps hinder such action, and that n -type and p -type conductors behave in opposite fashion when employed as photocatalysts. Using ferrites as catalysts in an acceptor reaction, the electron transfer concept was confirmed. It would be desirable to have available for these studies a number of well-understood acceptor- and donor-type reactions. Of particular interest are those reactions in which one of the reactants acts as a donor while the other behaves as an acceptor. A new reaction of this kind, the interaction of nitrous oxide and ammonia, has been studied from the point of view of kinetics and electronic influence." @default.
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- W86229331 date "1957-01-01" @default.
- W86229331 modified "2023-09-24" @default.
- W86229331 title "24 Photochemical and Kinetic Studies of Electronic Reaction Mechanisms" @default.
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- W86229331 doi "https://doi.org/10.1016/s0360-0564(08)60171-6" @default.
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