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• W1750519594 startingPage "P69" @default.
• W1750519594 abstract "In the context of the search for fundamental size effects regarding electrical conduction, we analyze the transition from semi-infinite or isolated to overlapped depletion layers in appreciably dense nanocrystalline ceramics occurring if the grain size becomes smaller than . At these small grain sizes, the bulk impedance signal that is seen clearly for microcrystalline samples disappears, leaving only one impedance response, which can be attributed to the space-charge zones. Space-charge potentials and Mott–Schottky lengths are calculated and shown to be consistent with the assumption of the mesoscopic condition. In accordance with the increased homogeneity of the mesoscopic situation in an sample, and unlike for microcrystalline samples, the impedance response is characterized by almost an ideal capacitance that no longer originates from space-charge polarization. These conclusions are corroborated by detailed numerical calculations using linear irreversible thermodynamics." @default.
• W1750519594 created "2016-06-24" @default.
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• W1750519594 date "2007-01-01" @default.
• W1750519594 modified "2023-09-23" @default.
• W1750519594 title "Mesoscopic Hole Conduction in Nanocrystalline SrTiO[sub 3]" @default.
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• W1750519594 doi "https://doi.org/10.1149/1.2716555" @default.
• W1750519594 hasPublicationYear "2007" @default.
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