FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1968045007> ?p ?o ?g. }

• W1968045007 endingPage "9601" @default.
• W1968045007 startingPage "9600" @default.
• W1968045007 abstract "Scanning electrochemical microscopy was used to probe the influence of a driving force on the heterogeneous electron transfer (ET) processes at the externally polarized water/1,2-dichloroethane interface. Being a part of the driving force, the Galvani potential difference at the interface, Deltaowphi, can be quantitatively controlled in a wide range, allowing the precise measurements of the rate constants of the ET reactions. Two opposite systems were chosen in this work. One was 5,10,15,20-tetraphenyl 21H,23H-porphyrin zinc (ZnPor, O)/Fe(CN)64- (W), and the other was TCNQ (O)/Fe(CN)63- (W). For both systems studied, the relations between the rate constant and the Deltaowphi were of parabolic shape; that is, the rate constants increased initially with the Deltaowphi until reaching a maximum and then decreased steadily as the Deltaowphi increased further. This is in accordance with the prediction of the Marcus theory. To our knowledge, this is the first report that the Marcus inverted region can be observed electrochemically at an unmodified liquid/liquid interface with only one redox couple at each phase. The effect of the concentrations of the organic supporting electrolyte has also been discussed in detail." @default.
• W1968045007 created "2016-06-24" @default.
• W1968045007 creator A5005228021 @default.
• W1968045007 creator A5015556629 @default.
• W1968045007 creator A5023587499 @default.
• W1968045007 creator A5026802483 @default.
• W1968045007 creator A5028720605 @default.
• W1968045007 creator A5071153582 @default.
• W1968045007 creator A5081914107 @default.
• W1968045007 date "2003-07-19" @default.
• W1968045007 modified "2023-10-18" @default.
• W1968045007 title "Observation of the Marcus Inverted Region of Electron Transfer Reactions at a Liquid/Liquid Interface" @default.
• W1968045007 cites W1978213786 @default.
• W1968045007 cites W1985666828 @default.
• W1968045007 cites W2009827605 @default.
• W1968045007 cites W2041647910 @default.
• W1968045007 cites W2059183494 @default.
• W1968045007 cites W2121096691 @default.
• W1968045007 cites W2334376416 @default.
• W1968045007 cites W89178911 @default.
• W1968045007 doi "https://doi.org/10.1021/ja0362297" @default.
• W1968045007 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12904021" @default.
• W1968045007 hasPublicationYear "2003" @default.
• W1968045007 type Work @default.
• W1968045007 sameAs 1968045007 @default.
• W1968045007 citedByCount "58" @default.
• W1968045007 countsByYear W19680450072012 @default.
• W1968045007 countsByYear W19680450072014 @default.
• W1968045007 countsByYear W19680450072015 @default.
• W1968045007 countsByYear W19680450072016 @default.
• W1968045007 countsByYear W19680450072017 @default.
• W1968045007 countsByYear W19680450072018 @default.
• W1968045007 countsByYear W19680450072020 @default.
• W1968045007 countsByYear W19680450072021 @default.
• W1968045007 countsByYear W19680450072022 @default.
• W1968045007 countsByYear W19680450072023 @default.
• W1968045007 crossrefType "journal-article" @default.
• W1968045007 hasAuthorship W1968045007A5005228021 @default.
• W1968045007 hasAuthorship W1968045007A5015556629 @default.
• W1968045007 hasAuthorship W1968045007A5023587499 @default.
• W1968045007 hasAuthorship W1968045007A5026802483 @default.
• W1968045007 hasAuthorship W1968045007A5028720605 @default.
• W1968045007 hasAuthorship W1968045007A5071153582 @default.
• W1968045007 hasAuthorship W1968045007A5081914107 @default.
• W1968045007 hasConcept C113196181 @default.
• W1968045007 hasConcept C121332964 @default.
• W1968045007 hasConcept C123669783 @default.
• W1968045007 hasConcept C147120987 @default.
• W1968045007 hasConcept C147789679 @default.
• W1968045007 hasConcept C148898269 @default.
• W1968045007 hasConcept C17525397 @default.
• W1968045007 hasConcept C178790620 @default.
• W1968045007 hasConcept C179104552 @default.
• W1968045007 hasConcept C185592680 @default.
• W1968045007 hasConcept C18762648 @default.
• W1968045007 hasConcept C2777869211 @default.
• W1968045007 hasConcept C2778895018 @default.
• W1968045007 hasConcept C3017397382 @default.
• W1968045007 hasConcept C43617362 @default.
• W1968045007 hasConcept C44280652 @default.
• W1968045007 hasConcept C52859227 @default.
• W1968045007 hasConcept C55904794 @default.
• W1968045007 hasConcept C62520636 @default.
• W1968045007 hasConcept C68801617 @default.
• W1968045007 hasConcept C74650414 @default.
• W1968045007 hasConcept C89169741 @default.
• W1968045007 hasConcept C93391505 @default.
• W1968045007 hasConcept C97355855 @default.
• W1968045007 hasConceptScore W1968045007C113196181 @default.
• W1968045007 hasConceptScore W1968045007C121332964 @default.
• W1968045007 hasConceptScore W1968045007C123669783 @default.
• W1968045007 hasConceptScore W1968045007C147120987 @default.
• W1968045007 hasConceptScore W1968045007C147789679 @default.
• W1968045007 hasConceptScore W1968045007C148898269 @default.
• W1968045007 hasConceptScore W1968045007C17525397 @default.
• W1968045007 hasConceptScore W1968045007C178790620 @default.
• W1968045007 hasConceptScore W1968045007C179104552 @default.
• W1968045007 hasConceptScore W1968045007C185592680 @default.
• W1968045007 hasConceptScore W1968045007C18762648 @default.
• W1968045007 hasConceptScore W1968045007C2777869211 @default.
• W1968045007 hasConceptScore W1968045007C2778895018 @default.
• W1968045007 hasConceptScore W1968045007C3017397382 @default.
• W1968045007 hasConceptScore W1968045007C43617362 @default.
• W1968045007 hasConceptScore W1968045007C44280652 @default.
• W1968045007 hasConceptScore W1968045007C52859227 @default.
• W1968045007 hasConceptScore W1968045007C55904794 @default.
• W1968045007 hasConceptScore W1968045007C62520636 @default.
• W1968045007 hasConceptScore W1968045007C68801617 @default.
• W1968045007 hasConceptScore W1968045007C74650414 @default.
• W1968045007 hasConceptScore W1968045007C89169741 @default.
• W1968045007 hasConceptScore W1968045007C93391505 @default.
• W1968045007 hasConceptScore W1968045007C97355855 @default.
• W1968045007 hasIssue "32" @default.
• W1968045007 hasLocation W19680450071 @default.
• W1968045007 hasLocation W19680450072 @default.
• W1968045007 hasOpenAccess W1968045007 @default.
• W1968045007 hasPrimaryLocation W19680450071 @default.
• W1968045007 hasRelatedWork W1964716344 @default.

• next