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- W1969133684 abstract "A simple lattice-gas model for the reaction of CO and NO on an Na-modified surface of a square lattice is studied. The crucial property of the model is Na-induced dissociation of NO, which triggers the catalytic reaction. Some interesting features are added to the phase diagram when the range of Na-induced NO dissociation is studied in the nearest and the next-nearest neighbourhood. The moment CO partial pressure (yCO) departs from zero, the continuous production of CO2 and N2 starts. This production remains continuous until a point where the catalytic activity stops and the surface is poisoned with a combination of CO, N and O. The value of poisoning point depends upon the value of Na concentration on the surface." @default.
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- W1969133684 date "2002-04-19" @default.
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- W1969133684 title "The effect of Na concentration on the kinetic phase transitions of a monomer-dimer reaction system on Na-promoted surface" @default.
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