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- W1969366933 abstract "Amorphous oxide and oxynitride lithium electrolyte thin films were synthesized by r.f. magnetron sputtering of lithium silicates and lithium phosphates in Ar, Ar + O2, Ar + N2, or N2. The composition, structure, and electrical properties of the films were characterized using ion and electron beam, X-ray, optical, photoelectron, and a.c. impedance techniques. For the lithium phosphosilicate films, lithium ion conductivities as high as 1.4 × 10−6 S/cm at 25 °C were observed, but none of these films selected for extended testing were stable in contact with lithium. On the other hand, a new thin-film lithium phosphorus oxynitride electrolyte, synthesized by sputtering Li3PO4 in pure N2, was found to have a conductivity of 2 × 10-6 S/cm at 25 °C and excellent long-term stability in contact with lithium. Thin-films cells consisting of a 1 μm thick amorphous V2O5 cathode, a 1 μm thick oxynitride electrolyte film, and a 5 μm thick lithium anode were cycled between 3.7 and 1.5 V using discharge rates of up to 100 μA/cm2 and charge rates of up to 20 μA/cm2. The open-circuit voltage of 3.6 to 3.7 V of fully-charged cells remained virtually unchanged after months of storage." @default.
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- W1969366933 date "1993-03-01" @default.
- W1969366933 modified "2023-10-14" @default.
- W1969366933 title "Fabrication and characterization of amorphous lithium electrolyte thin films and rechargeable thin-film batteries" @default.
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- W1969366933 doi "https://doi.org/10.1016/0378-7753(93)80106-y" @default.
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