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- W1970183670 abstract "The objective of this effort is to explore the substitution of the A-site in an A2MgMoO6 perovskite with Sr and Ba to improve the sulfur tolerance of solid oxide fuel cells (SOFCs). Perovskites have demonstrated superior sulfur tolerance but lack the high conductivity and catalytic activity of Ni/YSZ cermets. Sr2MgMoO6, a double perovskite, has been suggested as a material of interest because of its relatively high conductivity and catalytic potential. This study summarizes the synthesis of A2MgMoO6 (A = Sr,Ba) through sol–gel methods. The conductivity of the two samples was measured from thin pressed disks. Electrochemical performance of the specimens was performed by pasting the material onto an LSGM disk and stability was measured in sulfurous H2 (140 ppm H2S). Both SMMO and BMMO demonstrated superior stability when exposed to 140 ppm of H2S as compared to Ni/YSZ, but did exhibit performance degradations due to sulfur accumulation in the buffer layer." @default.
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- W1970183670 date "2013-06-01" @default.
- W1970183670 modified "2023-09-27" @default.
- W1970183670 title "A2MgMoO6 (A = Sr,Ba) for use as sulfur tolerant anodes" @default.
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- W1970183670 doi "https://doi.org/10.1016/j.jpowsour.2013.01.004" @default.
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