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• W1970889663 abstract "Total photoabsorption cross-sections and peak assignments were presented for C(1s) excited CF3CN. It was found that fragmentation of the core-excited CF3CN molecule competes with intramolecular energy redistribution on the basis of two measurements: One is the analysis of the kinetic energies of the CF3+, CF2+, CF+, F+ and CN+ fragment ions in angle-resolved mass spectra observed by using a linear time-of-flight mass spectrometer. This is the first observation that the kinetic energy distribution of fragment ions depends on the site of excitation. The other is site-selective photofragmentation by use of a reflectron type mass spectrometer. These experiments strongly suggest that the CF3 group acts as an effective internal energy reservoir." @default.
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• W1970889663 date "2002-05-01" @default.
• W1970889663 modified "2023-10-11" @default.
• W1970889663 title "Fragmentation competing with energy relaxation in core-excited CF3CN" @default.
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• W1970889663 doi "https://doi.org/10.1016/s0368-2048(02)00030-0" @default.
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