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- W1983702947 abstract "A novel dyad 2 based on C60 and bis(4‘-tert-butylbiphenyl-4-yl)aniline (BBA) donor has been synthesized and characterized. Cyclic voltammetry (CV) and UV−vis spectra of 2, 61-phenyl-1, 2-methanofullerene[60] 4, 1,2-methanofullerene[60] 5, and BBA were measured and analyzed. CV measurements showed that a reversible oxidation wave of 2 was positively shifted by 40 mV compared to that of BBA. More remarkably, comparing UV−vis spectra of 2 and 5 shows the big hyperchromic effect of 2 on a broad band at 500 nm despite lacking of more than 400 nm of absorbance for BBA. These results indicate obvious evidence of intramolecular charge-transfer interactions between C60-moiety and BBA." @default.
- W1983702947 created "2016-06-24" @default.
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- W1983702947 date "2001-04-17" @default.
- W1983702947 modified "2023-10-16" @default.
- W1983702947 title "Intramolecular Charge-Transfer Interaction in a New Dyad Based on C<sub>60</sub> and Bis(4‘-<i>tert</i>-butylbiphenyl-4-yl)aniline (BBA) Donor" @default.
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- W1983702947 doi "https://doi.org/10.1021/jo001100q" @default.
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