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• W1986173880 abstract "Assembly of a semi-rigid tripodal ligand, 3,5-bis(4-carboxyphenoxy)benzoic acid (H3bpa), with Ln2O3 (Ln = Dy for 1 and Er for 2) under hydrothermal condition produces two three-dimensional (3-D) lanthanide–organic frameworks (LnOFs), [Dy2(bpa)2(H2O)3] (1) and [Er4(bpa)4(H2O)6](H2O) (2). Single crystal X-ray diffraction indicates that LnOFs 1 and 2 involve different one-dimensional (1-D) rod-shaped metal-carboxylate secondary building units (SBUs), which are further extended to afford two different 3-D frameworks via the linkage of bpa3 − ligands. The results demonstrate that the diverse conformations and coordination modes of bpa3 − ligands play a key role on the formation of the final framework structures. Temperature-dependent magnetic susceptibility measurements reveal the presence of LnIII⋯LnIII ferromagnetic interactions in both LnOFs." @default.
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• W1986173880 date "2015-06-01" @default.
• W1986173880 modified "2023-10-15" @default.
• W1986173880 title "Two magnetic lanthanide–organic frameworks based on semi-rigid tripodal multicarboxylate ligand and different rod-shaped SBUs" @default.
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• W1986173880 doi "https://doi.org/10.1016/j.inoche.2015.03.046" @default.
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