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• W1987036699 abstract "Using a combination of low-temperature scanning tunneling microscopy and density functional theory it is demonstrated how the nature of an inert host metal of an alloy can affect the thermodynamics and kinetics of a reaction pathway in a much more profound way than simply a dilution, electronic, or geometric effect. This study reveals that individual, isolated Pd atoms can promote ${mathrm{H}}_{2}$ dissociation and spillover onto a Cu(111) surface, but that the same mechanism is not observed for an identical array of Pd atoms in Au(111)." @default.
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• W1987036699 date "2009-12-10" @default.
• W1987036699 modified "2023-10-12" @default.
• W1987036699 title "Hydrogen Dissociation and Spillover on Individual Isolated Palladium Atoms" @default.
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• W1987036699 doi "https://doi.org/10.1103/physrevlett.103.246102" @default.
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