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• W1992019985 abstract "Abstract A step‐growth alternating copolymerization of monomers A 2 and B 3 was studied by an off‐lattice Monte‐Carlo simulation. In the random systems, i.e. with no substitution effect, the polymerization leads to gel formation provided the molar ratio of monomers is not very far from the stoichiometric one (A 2 : B 3 ≈ 3: 2) and the reaction is carried out in one batch. A substantial deviation from the stoichiometric ratio may halt gelation altogether, even at conversions of the minority functional groups approaching unity. We demonstrate that in these non‐gelling off‐stoichiometric systems, one can force the system to gel, after all, without altering the kinetics or diffusion parameters of the reaction. The clue is to carry out the reaction in steps." @default.
• W1992019985 created "2016-06-24" @default.
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• W1992019985 date "2010-05-01" @default.
• W1992019985 modified "2023-09-25" @default.
• W1992019985 title "Forced Gelation in an Off-Stoichiometric Copolymerization of A2 and B3 Monomers" @default.
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• W1992019985 doi "https://doi.org/10.1002/masy.201050531" @default.
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