FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1996456502> ?p ?o ?g. }

• W1996456502 endingPage "503" @default.
• W1996456502 startingPage "502" @default.
• W1996456502 abstract "A “two-silicon cycle” for the highly efficient intermolecular chirality transfer from silicon to carbon (98−99% ct) in the palladium-catalyzed hydrosilylation of norbornenes emerges from an investigation involving catalytic crossover experiments with isotopically labeled silicon-stereogenic silanes. A key outcome of these experiments, which are supported by product-distribution modeling, is the conclusion that the chirality transfer arises from thermodynamically controlled reversible silapalladation of the alkene rather than from kinetic control during irreversible σ-bond metathesis of the resulting β-silyl σ-alkyl palladium complex with chiral silane." @default.
• W1996456502 created "2016-06-24" @default.
• W1996456502 creator A5002792140 @default.
• W1996456502 creator A5004567326 @default.
• W1996456502 creator A5009230738 @default.
• W1996456502 creator A5090088618 @default.
• W1996456502 date "2006-12-22" @default.
• W1996456502 modified "2023-10-18" @default.
• W1996456502 title "Intermolecular Chirality Transfer from Silicon to Carbon: Interrogation of the Two-Silicon Cycle for Pd-Catalyzed Hydrosilylation by Stereoisotopochemical Crossover" @default.
• W1996456502 cites W2034814637 @default.
• W1996456502 cites W2039781585 @default.
• W1996456502 cites W2041112384 @default.
• W1996456502 cites W2047659473 @default.
• W1996456502 cites W2048676985 @default.
• W1996456502 cites W2085086647 @default.
• W1996456502 cites W2135148200 @default.
• W1996456502 cites W2166706290 @default.
• W1996456502 doi "https://doi.org/10.1021/ja067780h" @default.
• W1996456502 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17227008" @default.
• W1996456502 hasPublicationYear "2006" @default.
• W1996456502 type Work @default.
• W1996456502 sameAs 1996456502 @default.
• W1996456502 citedByCount "82" @default.
• W1996456502 countsByYear W19964565022012 @default.
• W1996456502 countsByYear W19964565022013 @default.
• W1996456502 countsByYear W19964565022014 @default.
• W1996456502 countsByYear W19964565022015 @default.
• W1996456502 countsByYear W19964565022016 @default.
• W1996456502 countsByYear W19964565022017 @default.
• W1996456502 countsByYear W19964565022018 @default.
• W1996456502 countsByYear W19964565022019 @default.
• W1996456502 countsByYear W19964565022020 @default.
• W1996456502 countsByYear W19964565022021 @default.
• W1996456502 countsByYear W19964565022022 @default.
• W1996456502 countsByYear W19964565022023 @default.
• W1996456502 crossrefType "journal-article" @default.
• W1996456502 hasAuthorship W1996456502A5002792140 @default.
• W1996456502 hasAuthorship W1996456502A5004567326 @default.
• W1996456502 hasAuthorship W1996456502A5009230738 @default.
• W1996456502 hasAuthorship W1996456502A5090088618 @default.
• W1996456502 hasConcept C121332964 @default.
• W1996456502 hasConcept C124668440 @default.
• W1996456502 hasConcept C134195300 @default.
• W1996456502 hasConcept C146686406 @default.
• W1996456502 hasConcept C153914509 @default.
• W1996456502 hasConcept C161790260 @default.
• W1996456502 hasConcept C166950319 @default.
• W1996456502 hasConcept C178790620 @default.
• W1996456502 hasConcept C185592680 @default.
• W1996456502 hasConcept C20621625 @default.
• W1996456502 hasConcept C2776254738 @default.
• W1996456502 hasConcept C2778024649 @default.
• W1996456502 hasConcept C2778183973 @default.
• W1996456502 hasConcept C2778421718 @default.
• W1996456502 hasConcept C2780987620 @default.
• W1996456502 hasConcept C32909587 @default.
• W1996456502 hasConcept C44228677 @default.
• W1996456502 hasConcept C502130503 @default.
• W1996456502 hasConcept C521977710 @default.
• W1996456502 hasConcept C52703039 @default.
• W1996456502 hasConcept C5304478 @default.
• W1996456502 hasConcept C544956773 @default.
• W1996456502 hasConcept C62520636 @default.
• W1996456502 hasConcept C75473681 @default.
• W1996456502 hasConcept C7602139 @default.
• W1996456502 hasConceptScore W1996456502C121332964 @default.
• W1996456502 hasConceptScore W1996456502C124668440 @default.
• W1996456502 hasConceptScore W1996456502C134195300 @default.
• W1996456502 hasConceptScore W1996456502C146686406 @default.
• W1996456502 hasConceptScore W1996456502C153914509 @default.
• W1996456502 hasConceptScore W1996456502C161790260 @default.
• W1996456502 hasConceptScore W1996456502C166950319 @default.
• W1996456502 hasConceptScore W1996456502C178790620 @default.
• W1996456502 hasConceptScore W1996456502C185592680 @default.
• W1996456502 hasConceptScore W1996456502C20621625 @default.
• W1996456502 hasConceptScore W1996456502C2776254738 @default.
• W1996456502 hasConceptScore W1996456502C2778024649 @default.
• W1996456502 hasConceptScore W1996456502C2778183973 @default.
• W1996456502 hasConceptScore W1996456502C2778421718 @default.
• W1996456502 hasConceptScore W1996456502C2780987620 @default.
• W1996456502 hasConceptScore W1996456502C32909587 @default.
• W1996456502 hasConceptScore W1996456502C44228677 @default.
• W1996456502 hasConceptScore W1996456502C502130503 @default.
• W1996456502 hasConceptScore W1996456502C521977710 @default.
• W1996456502 hasConceptScore W1996456502C52703039 @default.
• W1996456502 hasConceptScore W1996456502C5304478 @default.
• W1996456502 hasConceptScore W1996456502C544956773 @default.
• W1996456502 hasConceptScore W1996456502C62520636 @default.
• W1996456502 hasConceptScore W1996456502C75473681 @default.
• W1996456502 hasConceptScore W1996456502C7602139 @default.
• W1996456502 hasIssue "3" @default.
• W1996456502 hasLocation W19964565021 @default.
• W1996456502 hasLocation W19964565022 @default.
• W1996456502 hasOpenAccess W1996456502 @default.
• W1996456502 hasPrimaryLocation W19964565021 @default.
• W1996456502 hasRelatedWork W1537124858 @default.
• W1996456502 hasRelatedWork W1996456502 @default.
• W1996456502 hasRelatedWork W2030547596 @default.

• next