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• W2000924823 abstract "The kinetics of iron(III) hydrolysis and precipitation in aqueous glycine solutions were studied by cathodic voltammetry with a mercury drop electrode. The kinetics was controlled by changing ionic strength ( I ), pH and glycine concentration. Voltammetric measurements clearly showed formation and dissociation of a soluble Fe(III)–glycine complex, formation of iron(III) hydroxide and its precipitation. The rate constants of iron(III) hydroxide precipitation were assessed. The precipitation is first-order with respect to dissolved inorganic iron(III). The calculated rate constants of iron(III) precipitation varied from 0.18 × 10 –5 s –1 (at 0.2 M total glycine, pH 7.30, I = 0.6 mol dm –3 ) to 2.22 × 10 –3 s –1 (at 0.1 M total glycine, pH 7.30, I = 0.2 mol dm –3 ). At 0.5 M total glycine and I = 0.6 mol dm –3 , the iron(III) precipitation was not observed." @default.
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• W2000924823 date "2009-01-01" @default.
• W2000924823 modified "2023-09-24" @default.
• W2000924823 title "Kinetics of iron(III) hydrolysis and precipitation in aqueous glycine solutions assessed by voltammetry" @default.
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• W2000924823 doi "https://doi.org/10.1135/cccc2009103" @default.
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