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• W2003138002 endingPage "432" @default.
• W2003138002 startingPage "422" @default.
• W2003138002 abstract "We have used density functional theory to investigate the reductive elimination from platinum(IV) structures of the form L2PtR4 where L = PMe3, PH3, PF3, CO, NH3 and R = vinyl, Me. We conclude that reductive elimination occurs via the L-predissociation pathway for R = Me, irrespective of ligand L. But when R = vinyl, direct elimination is the preferred pathway if the L ligand is PMe3; otherwise both pathways are competitive for R = vinyl. We also note that if L is more π-electron accepting and less σ-electron donating, the reductive elimination from the six-coordinate complexes L2PtR4 will be more rapid. Reductive elimination from the five-coordinate complexes LPtR4 proceeds more easily if the ligand trans to the two R groups being coupled is more σ-electron donating and the ligands cis to the two R groups are more π-electron accepting." @default.
• W2003138002 created "2016-06-24" @default.
• W2003138002 creator A5008546864 @default.
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• W2003138002 creator A5085531925 @default.
• W2003138002 creator A5089185587 @default.
• W2003138002 date "2011-01-05" @default.
• W2003138002 modified "2023-10-16" @default.
• W2003138002 title "Insight into the Mechanism of R−R Reductive Elimination from the Six-Coordinate d⁶ Complexes L₂Pt(R)₄ (R = vinyl, Me)" @default.
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