FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2003669059> ?p ?o ?g. }

• W2003669059 endingPage "2361" @default.
• W2003669059 startingPage "2339" @default.
• W2003669059 abstract "Abstract Some recent achievements in condensed phase molecular charge transfer theory are overviewed, with focus on interfacial electrochemical electron transfer (ET). Elements of available and new formalism are addressed in 2 Some observations on electrochemical electron transfer , 3 Some new observations in electrochemical et formalism . New elements considered are, firstly, a new convenient parametric scheme for calculation of the rate constant and electrochemical current. The scheme goes beyond the commonly used quadratic free energy relations and extends straightforwardly to vibrational frequency changes, anharmonic nuclear motion, and nuclear tunnelling in local and vibrationally dispersive environmental modes. Other new elements addressed are adiabatic electrochemical processes, and self-consistent calculations of the electronic–vibrational interaction in long-range ET. Self-consistency leads to non-linear electronic–vibrational features. These enhance charge transfer both by increasing the electronic tunnel factor and by decreasing the activation Gibbs free energy. Elements of charge transfer formalism are followed in Section 4 by a discussion of the theoretical basis of several electrochemical ET systems. Attention is given to electrochemical ET across well-characterized thin films, hot electron electrochemistry, electrochemistry at superconducting electrodes, and ET near a temperature or field induced high order phase transition. Particular attention is given to in situ electrochemical scanning tunnelling microscopy where a dielectric continuum or configurationally fluctuating water molecules in the tunnel gap, molecular adsorbates, and bias voltage and overvoltage spectroscopy for different tunnelling mechanisms, are considered. Section 5 gives a short discussion of some new views on proton conduction in strongly hydrogen bonded systems, and of the electrochemical dihydrogen evolution reaction, with focus on low-temperature features. This part is concluded by some perspectives in areas of molecular scale science (nanotechnology, molecular electronics) which can be expected to hold new cases for pure and applied molecular charge transfer theory." @default.
• W2003669059 created "2016-06-24" @default.
• W2003669059 creator A5034711870 @default.
• W2003669059 creator A5065984968 @default.
• W2003669059 date "2000-05-01" @default.
• W2003669059 modified "2023-10-17" @default.
• W2003669059 title "Theory of electron transfer at electrified interfaces" @default.
• W2003669059 cites W1154975637 @default.
• W2003669059 cites W1485300768 @default.
• W2003669059 cites W1512361887 @default.
• W2003669059 cites W1530403363 @default.
• W2003669059 cites W1530687917 @default.
• W2003669059 cites W1553660633 @default.
• W2003669059 cites W1576668315 @default.
• W2003669059 cites W1577215369 @default.
• W2003669059 cites W159424003 @default.
• W2003669059 cites W1602932472 @default.
• W2003669059 cites W177061443 @default.
• W2003669059 cites W1966916735 @default.
• W2003669059 cites W1967390492 @default.
• W2003669059 cites W1967443677 @default.
• W2003669059 cites W1968605760 @default.
• W2003669059 cites W1968800391 @default.
• W2003669059 cites W1969561803 @default.
• W2003669059 cites W1970327813 @default.
• W2003669059 cites W1970544232 @default.
• W2003669059 cites W1970641611 @default.
• W2003669059 cites W1971490917 @default.
• W2003669059 cites W1972638895 @default.
• W2003669059 cites W1973676678 @default.
• W2003669059 cites W1974027684 @default.
• W2003669059 cites W1974767172 @default.
• W2003669059 cites W1975834385 @default.
• W2003669059 cites W1975834451 @default.
• W2003669059 cites W1976647696 @default.
• W2003669059 cites W1976958038 @default.
• W2003669059 cites W1977105353 @default.
• W2003669059 cites W1978143491 @default.
• W2003669059 cites W1978209529 @default.
• W2003669059 cites W1978302358 @default.
• W2003669059 cites W1978476140 @default.
• W2003669059 cites W1978907111 @default.
• W2003669059 cites W1979186401 @default.
• W2003669059 cites W1979774492 @default.
• W2003669059 cites W1980042091 @default.
• W2003669059 cites W1981247543 @default.
• W2003669059 cites W1982839983 @default.
• W2003669059 cites W1983110361 @default.
• W2003669059 cites W1983293330 @default.
• W2003669059 cites W1984708418 @default.
• W2003669059 cites W1985214418 @default.
• W2003669059 cites W1985854442 @default.
• W2003669059 cites W1987757695 @default.
• W2003669059 cites W1988133899 @default.
• W2003669059 cites W1989336153 @default.
• W2003669059 cites W1991419946 @default.
• W2003669059 cites W1992686506 @default.
• W2003669059 cites W1993108195 @default.
• W2003669059 cites W1993972400 @default.
• W2003669059 cites W1996749780 @default.
• W2003669059 cites W1998344939 @default.
• W2003669059 cites W1998904893 @default.
• W2003669059 cites W1999120799 @default.
• W2003669059 cites W1999502246 @default.
• W2003669059 cites W1999724837 @default.
• W2003669059 cites W2001192048 @default.
• W2003669059 cites W2002265279 @default.
• W2003669059 cites W2005143966 @default.
• W2003669059 cites W2006395743 @default.
• W2003669059 cites W2007519194 @default.
• W2003669059 cites W2008250160 @default.
• W2003669059 cites W2008638472 @default.
• W2003669059 cites W2008912569 @default.
• W2003669059 cites W2008961125 @default.
• W2003669059 cites W2009441880 @default.
• W2003669059 cites W2011948135 @default.
• W2003669059 cites W2012127795 @default.
• W2003669059 cites W2012595815 @default.
• W2003669059 cites W2016634010 @default.
• W2003669059 cites W2016935779 @default.
• W2003669059 cites W2017121669 @default.
• W2003669059 cites W2018839257 @default.
• W2003669059 cites W2019525319 @default.
• W2003669059 cites W2020856435 @default.
• W2003669059 cites W2021628041 @default.
• W2003669059 cites W2021856457 @default.
• W2003669059 cites W2022022904 @default.
• W2003669059 cites W2023636818 @default.
• W2003669059 cites W2025161633 @default.
• W2003669059 cites W2027327117 @default.
• W2003669059 cites W2028896809 @default.
• W2003669059 cites W2030586202 @default.
• W2003669059 cites W2030623135 @default.
• W2003669059 cites W2030728686 @default.
• W2003669059 cites W2031383629 @default.
• W2003669059 cites W2033396717 @default.
• W2003669059 cites W2033575338 @default.
• W2003669059 cites W2034183800 @default.

• next