Matches in SemOpenAlex for { <https://semopenalex.org/work/W2009514531> ?p ?o ?g. }
- W2009514531 endingPage "667" @default.
- W2009514531 startingPage "659" @default.
- W2009514531 abstract "A combined atomic resonance absorption spectrometry and single-pulse shock tube investigation on the thermal decomposition of benzonitrile was performed behind reflected shocks in pressurized driver shock tubes. The single-pulse shock tube experiments covered the temperature range 1350–1750 K at overall densities of ∼×10 −5 mol/cm 3 and the ARAS measurements covered the range 1500–1900 K at approximately the same densities. The resonance absorption measurements were done to provide rate parameters for two key reactions in the system: (1) C 6 H 5 CN→C 6 H 4 CN·+H· and (2) C 6 H 5 CH+H·→ products. The values obtained were k 1 =7.6×10 15 exp(−16×10 3 / RT ) s −1 and k 2 =2.2×10 14 exp(−12.6×10 3 / RT ) cm 3 mol −1 s −1 , where R is expressed in units of cal/(K mol). GC analyses of postshock samples obtained in the single-pulse shock tube experiments revealed the presence of the folowing decomposition products: C 2 H 2 , C 4 H 2 , C 6 H 6 , HCN, CH≡C−CN, C 6 H 5 ≡CH, and C 6 H 5 −C 6 H 5 . The overall rate constant for benzonitrile decomposition (in terms of a first-order constant) is given by k total =1.15×10 14 exp(−87.8×10 3 / RT )s −1 . A reaction scheme containing 21 species and 32 elementary reaction was constructed to account for the experimental roduct disribution. The results of the computer simulation show that the decomposition of te open l -C 6 H 4 CN· radical is somewhat slower than the decomposition of l -C 6 H 5 . . Arrhenius rate parameters for the product of the decomposition products decomposition of l -C 6 H 5 . . Arrhenius rate parameters for the production rates of the decomposition products are given and a discussion of the mechanism is presented." @default.
- W2009514531 created "2016-06-24" @default.
- W2009514531 creator A5017793306 @default.
- W2009514531 creator A5046072802 @default.
- W2009514531 creator A5079645349 @default.
- W2009514531 creator A5085626875 @default.
- W2009514531 date "1996-01-01" @default.
- W2009514531 modified "2023-09-27" @default.
- W2009514531 title "Thermal decomposition of benonitrile: A combined single-pulse shock tube-aras investigation" @default.
- W2009514531 cites W1993301841 @default.
- W2009514531 cites W1993845991 @default.
- W2009514531 cites W1999000724 @default.
- W2009514531 cites W2001938701 @default.
- W2009514531 cites W2002381656 @default.
- W2009514531 cites W2004201201 @default.
- W2009514531 cites W2017765069 @default.
- W2009514531 cites W2041135484 @default.
- W2009514531 cites W2045283896 @default.
- W2009514531 cites W2051368865 @default.
- W2009514531 cites W2059998406 @default.
- W2009514531 cites W2066513057 @default.
- W2009514531 cites W2067141602 @default.
- W2009514531 cites W2070443227 @default.
- W2009514531 cites W2102344646 @default.
- W2009514531 cites W2950719162 @default.
- W2009514531 cites W2953275372 @default.
- W2009514531 doi "https://doi.org/10.1016/s0082-0784(96)80273-6" @default.
- W2009514531 hasPublicationYear "1996" @default.
- W2009514531 type Work @default.
- W2009514531 sameAs 2009514531 @default.
- W2009514531 citedByCount "6" @default.
- W2009514531 countsByYear W20095145312016 @default.
- W2009514531 countsByYear W20095145312019 @default.
- W2009514531 countsByYear W20095145312021 @default.
- W2009514531 countsByYear W20095145312023 @default.
- W2009514531 crossrefType "journal-article" @default.
- W2009514531 hasAuthorship W2009514531A5017793306 @default.
- W2009514531 hasAuthorship W2009514531A5046072802 @default.
- W2009514531 hasAuthorship W2009514531A5079645349 @default.
- W2009514531 hasAuthorship W2009514531A5085626875 @default.
- W2009514531 hasConcept C113196181 @default.
- W2009514531 hasConcept C120665830 @default.
- W2009514531 hasConcept C121332964 @default.
- W2009514531 hasConcept C122881758 @default.
- W2009514531 hasConcept C124681953 @default.
- W2009514531 hasConcept C125287762 @default.
- W2009514531 hasConcept C126322002 @default.
- W2009514531 hasConcept C148898269 @default.
- W2009514531 hasConcept C155647269 @default.
- W2009514531 hasConcept C159985019 @default.
- W2009514531 hasConcept C160434732 @default.
- W2009514531 hasConcept C178790620 @default.
- W2009514531 hasConcept C185592680 @default.
- W2009514531 hasConcept C192562407 @default.
- W2009514531 hasConcept C2779953769 @default.
- W2009514531 hasConcept C2780167933 @default.
- W2009514531 hasConcept C2781300812 @default.
- W2009514531 hasConcept C39353612 @default.
- W2009514531 hasConcept C62520636 @default.
- W2009514531 hasConcept C70477161 @default.
- W2009514531 hasConcept C71924100 @default.
- W2009514531 hasConcept C93391505 @default.
- W2009514531 hasConcept C94915269 @default.
- W2009514531 hasConcept C97355855 @default.
- W2009514531 hasConceptScore W2009514531C113196181 @default.
- W2009514531 hasConceptScore W2009514531C120665830 @default.
- W2009514531 hasConceptScore W2009514531C121332964 @default.
- W2009514531 hasConceptScore W2009514531C122881758 @default.
- W2009514531 hasConceptScore W2009514531C124681953 @default.
- W2009514531 hasConceptScore W2009514531C125287762 @default.
- W2009514531 hasConceptScore W2009514531C126322002 @default.
- W2009514531 hasConceptScore W2009514531C148898269 @default.
- W2009514531 hasConceptScore W2009514531C155647269 @default.
- W2009514531 hasConceptScore W2009514531C159985019 @default.
- W2009514531 hasConceptScore W2009514531C160434732 @default.
- W2009514531 hasConceptScore W2009514531C178790620 @default.
- W2009514531 hasConceptScore W2009514531C185592680 @default.
- W2009514531 hasConceptScore W2009514531C192562407 @default.
- W2009514531 hasConceptScore W2009514531C2779953769 @default.
- W2009514531 hasConceptScore W2009514531C2780167933 @default.
- W2009514531 hasConceptScore W2009514531C2781300812 @default.
- W2009514531 hasConceptScore W2009514531C39353612 @default.
- W2009514531 hasConceptScore W2009514531C62520636 @default.
- W2009514531 hasConceptScore W2009514531C70477161 @default.
- W2009514531 hasConceptScore W2009514531C71924100 @default.
- W2009514531 hasConceptScore W2009514531C93391505 @default.
- W2009514531 hasConceptScore W2009514531C94915269 @default.
- W2009514531 hasConceptScore W2009514531C97355855 @default.
- W2009514531 hasIssue "1" @default.
- W2009514531 hasLocation W20095145311 @default.
- W2009514531 hasOpenAccess W2009514531 @default.
- W2009514531 hasPrimaryLocation W20095145311 @default.
- W2009514531 hasRelatedWork W1963697116 @default.
- W2009514531 hasRelatedWork W1964118816 @default.
- W2009514531 hasRelatedWork W1964205974 @default.
- W2009514531 hasRelatedWork W1984425275 @default.
- W2009514531 hasRelatedWork W2008990936 @default.
- W2009514531 hasRelatedWork W2011802819 @default.