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- W2009869238 abstract "The asymmetric hydration of α-benzyl-α-methylmalononitrile was examined by using chiral bifunctional catalysts. Enantiomer discrimination of the prochiral dinitrile in the presence of water was demonstrated with a well-defined bifunctional amido-Ru complex having N-sulfonyldiamine ligands, and providing the corresponding amidato(amine) complexes diastereoselectively. Under the catalytic conditions, the (R)-cyanoamide was successfully obtained without further hydrolysis to carboxylic acids." @default.
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- W2009869238 date "2010-05-01" @default.
- W2009869238 modified "2023-09-23" @default.
- W2009869238 title "Asymmetric nitrile-hydration with bifunctional ruthenium catalysts bearing chiral N-sulfonyldiamine ligands" @default.
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- W2009869238 doi "https://doi.org/10.1016/j.tetasy.2010.03.011" @default.
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