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- W2011114698 abstract "In this paper we have simulated both steady-state and time-resolved dynamic reaction measurements and directly compared them to experimental results. Effects such as internal diffusion resistance and site heterogeneity, which are commonly observed in supported metal catalysts, are included in the simulations presented here. Single-site Langmuir-Hinshelwood models fail to predict the rates of reaction measured during steady-state and dynamic operation. Both steady-state and time-resolved dynamic reaction measurements for two types of Pt/Al2O3 catalysts can be predicted by an elementary step model with a bimodal distribution of active sites. Diffusion resistance produced significant gas and surface concentration gradients inside the porous catalyst and suppressed the rate of CO2 production during the initial period of CO-on half-cycles. To our knowledge, this is the first work comparing steady-state and time-resolved dynamic CO oxidation measurements to an elementary step model incorporating internal diffusion resistance." @default.
- W2011114698 created "2016-06-24" @default.
- W2011114698 creator A5015915144 @default.
- W2011114698 date "1992-09-01" @default.
- W2011114698 modified "2023-09-27" @default.
- W2011114698 title "Modeling dynamic CO oxidation over Pt/Al2O3: Effects of intrapellet diffusion and site heterogeneity" @default.
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- W2011114698 doi "https://doi.org/10.1016/0021-9517(92)90146-9" @default.
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