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- W2018082022 abstract "The hydrogen-bonding effects of ethanol, phenol, and water on the electron-spin-resonance spectra of the anion radicals of 4-nitro- and 4-cyano-pyridine N-oxides, pyrazine mono- and di-N-oxides, and 4-nitropyridine electrochemically generated in dimethylformamide have been studied quantitatively. The equilibrium constant, K, pertinent to the hydrogen-bonding systems was determined on the basis of analyses of the variation in the hyperfine coupling constant caused by the addition of a proton donor. The active site in a radical anion participating in the hydrogenbonding interaction and the K values were then discussed on the basis of the theoretical calculation of the spin density and the coupling constant of the radicals in the hydrogen-bonding interaction. It has been pointed out that this sort of experiment in hydrogen bonding interaction is also useful for assigning the hyperfine coupling constant to a definite atom in a radical. Last, these K values are used to explain the mechanism of radical formatio..." @default.
- W2018082022 created "2016-06-24" @default.
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- W2018082022 date "1970-06-01" @default.
- W2018082022 modified "2023-10-13" @default.
- W2018082022 title "Hydrogen-bonding Effects on the Electron Spin Resonance Spectra of the Anion Radicals of Several Aromatic Amine<i>N</i>-Oxides" @default.
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