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• W2019917612 abstract "Five new compounds of alkali metal, indium, and bismuth were synthesized by direct fusion of the elements. The structures of these compounds, Na3In2Bi3 (I) (refined composition NaIn0.61(1)Bi, orthorhombic, Pnma, a=8.062(2), b=4.8684(8), and c=9.2455(9) Å), Na3InBi2 (II) (monoclinic, P21/c, a=18.841(3), b=9.235(1), and c=12.661(2) Å, β=98.67(2)°), K7In4Bi6 (III) (refined composition K4.71(3)In2.52(2)Bi4, tetragonal, P43, a=9.703(1), and c=17.519(4) Å), K11In6Bi9 (IV) (triclinic, P1, a=12.012(7), b=13.380(4), and c=13.695(4) Å, α=76.70(2), β=64.14(3), and γ=75.68(3)°), and Rb7In4Bi6 (V) (tetragonal, P43, a=9.915(2) and c=17.870(4) Å) are built of indium-centered tetrahedra of bismuth that are connected by corner- or/and edge-sharing and form different types of three-dimensional networks. All five compounds are diamagnetic and, therefore, electronically balanced, salt-like Zintl phases. According to EHMO calculations they are wide band-gap semiconductors." @default.
• W2019917612 created "2016-06-24" @default.
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• W2019917612 date "2002-02-01" @default.
• W2019917612 modified "2023-09-27" @default.
• W2019917612 title "Five Ternary Zintl Phases in the Systems Alkali-Metal–Indium–Bismuth" @default.
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• W2019917612 doi "https://doi.org/10.1006/jssc.2001.9423" @default.
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