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- W2019966170 abstract "A new mesogenic homologous series having a biphenyl moiety has been synthesized by condensing 4-hydroxy-4′-nitrobiphenyl- and methoxy-substituted 4-n-alkoxy cinnamoyl chlorides, and their liquid crystalline properties have been studied. All the members of the series are enantiotropic liquid crystals. The methyl to n-pentyl derivatives exhibit both Smectic A (SmA) and Nematic (N) phases; the higher members, starting with the n-hexyl derivative show only a SmA phase. The plot of transition temperatures versus number of carbon atoms in the alkoxy chain exhibits zig-zag pattern for Sm-N and N-Isotropic (Iso) transition temperature curves. The average thermal stability is compared with other related homologous series. The introduction of polar nitro group increases significant intermolecular force of attraction which stabilizes the molecular orientation. This results into the increase in the thermal stability of the system." @default.
- W2019966170 created "2016-06-24" @default.
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- W2019966170 date "2014-04-13" @default.
- W2019966170 modified "2023-10-05" @default.
- W2019966170 title "Synthesis and Mesomorphic Behavior of Calamitic Liquid Crystals with a Biphenyl Moiety" @default.
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- W2019966170 doi "https://doi.org/10.1080/15421406.2013.867228" @default.
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