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• W2019969726 abstract "Kinetic analysis of high-conversion free-radical polymerization is discussed in terms of the complete solution of the classical kinetic scheme, which involves initiation, propagation, termination, and chain-transfer reactions. Expressions for kinetics of formation of each species existing in the polymerization mixture are presented. To demonstrate the applicability of the mathematical model, monomer conversion and the formation of the insoluble polymer component in the dispersion polymerization of styrene and methyl methacrylate (MMA) in 2-propanol have been measured at 70 °C. The values obtained for kd and kp/kt1/2, where kd, kp, and kt are dissociation, propagation, and termination rate constants, respectively, are in agreement with those reported in the literature." @default.
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• W2019969726 date "1998-09-01" @default.
• W2019969726 modified "2023-09-24" @default.
• W2019969726 title "A Model of Complete Classical Treatment of Dispersion Radical Polymerization Kinetics" @default.
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• W2019969726 doi "https://doi.org/10.1021/ma9717956" @default.
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