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• W2019997507 startingPage "12367" @default.
• W2019997507 abstract "The transition of copper oxide thin films from CuO to ${mathrm{Cu}}_{2}$O during vacuum annealing has been studied by transmission electron microscopy and Rutherford backscattering spectroscopy. Dark field images show that isolated and large ${mathrm{Cu}}_{2}$O grains emerge from the small CuO grain matrix. The abrupt change in oxygen concentration across the phase boundary between CuO and ${mathrm{Cu}}_{2}$O in the reaction is different from the continuous change of $ensuremath{delta}$ in oxidation and reduction of the superconducting $mathrm{Y}{mathrm{Ba}}_{2}{mathrm{Cu}}_{3}{mathrm{O}}_{7ensuremath{-}ensuremath{delta}}$ oxide. The growth of ${mathrm{Cu}}_{2}$O grains is linear with time and has an activation energy of 1.1 eV. We propose that the discontinuous morphology of grain growth of ${mathrm{Cu}}_{2}$O is due to the migration of the ${mathrm{Cu}}_{2}$O-CuO phase boundary induced by oxygen out-diffusion along the moving phase boundary." @default.
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• W2019997507 date "1989-06-01" @default.
• W2019997507 modified "2023-09-26" @default.
• W2019997507 title "Oxygen-diffusion-induced phase boundary migration in copper oxide thin films" @default.
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• W2019997507 doi "https://doi.org/10.1103/physrevb.39.12367" @default.
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