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• W2021551036 abstract "One to 20 monolayers of Pd were deposited on Pt(1 1 1) and their electrochemical behavior was studied by cyclic voltammetry and impedance spectroscopy. The hydrogen adsorption and absorption is more reversible at deposits on Pt(1 1 1) as compared to Au(1 1 1), probably due to less strain and/or electronic effects. The quantity of hydrogen adsorbed/absorbed at 10 ML are however comparable at both supports. The charge transfer resistance is lower at 1 Pd ML in perchloric and sulfuric acids than for thicker layers, and it is lower at Pd/Pt(1 1 1) than at Pd/Au(1 1 1). The adsorption pseudocapacitance reaches a maximum at 0.214 V in sulfuric acid for 1 ML and there are two peaks at 0.214 V and 0.255 V for thicker layers. Crystal violet increases the reversibility of hydrogen absorption and inhibits hydrogen adsorption although some residual adsorption remains." @default.
• W2021551036 created "2016-06-24" @default.
• W2021551036 creator A5087533305 @default.
• W2021551036 creator A5088021563 @default.
• W2021551036 date "2008-09-01" @default.
• W2021551036 modified "2023-09-27" @default.
• W2021551036 title "Hydrogen adsorption/absorption on Pd/Pt(111) multilayers" @default.
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• W2021551036 doi "https://doi.org/10.1016/j.jelechem.2008.04.019" @default.
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