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• W2028045446 abstract "Studies of the vacuum-ultraviolet photolysis of HCClF2 and of HCCl2F isolated in argon and nitrogen matrices at 14°K have led to the infrared spectroscopic identification of the free radicals ClCF2 and FCCl2, respectively. Support for this identification has been obtained from studies of the vacuum-ultraviolet photolysis of DCClF2, of DCCl2F, and of H13CCl2F, as well as from studies of halogen-atom abstraction from CClF3 and from CCl3F by sodium atoms in an argon matrix environment. The CCl bonds of FCCl2, like those of CCl3 and of HCCl2, appear to be exceptionally strong. Gas-phase infrared spectral data are also reported for DCClF2 and for DCCl2F, not previously studied. Vibrational assignments are proposed for these two molecules, and data supporting the reassignment of one of the CF stretching fundamentals of HCClF2 are presented." @default.
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• W2028045446 date "1973-03-01" @default.
• W2028045446 modified "2023-09-24" @default.
• W2028045446 title "Matrix isolation study of the vacuum-ultraviolet photolysis of HCCIF2 and of HCCl2F. Infrared spectra of the parent molecules and of the ClCF2 and FCCl2 free radicals" @default.
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• W2028045446 doi "https://doi.org/10.1016/0022-2852(73)90209-9" @default.
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