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• W2031789686 abstract "Two new, user-friendly derivatives of triptycene containing AsH(2) and SiH(3) fragments were synthesized. Both solids are crystalline, air-stable compounds characterized by elevated melting points and resistance toward moisture. The highly reactive As-H and Si-H bonds are protected by the presence of the surrounding phenylene hydrogen atoms, which ensure a remarkable kinetic stabilization of these primary hydrides. After X-ray irradiation of a single crystal of triptycenesilane, a persistent silyl radical was trapped and characterized." @default.
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• W2031789686 date "2003-09-20" @default.
• W2031789686 modified "2023-10-10" @default.
• W2031789686 title "Kinetic Stabilization of Primary Hydrides of Main Group Elements. The Synthesis of an Air-Stable, Crystalline Arsine and Silane" @default.
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• W2031789686 doi "https://doi.org/10.1021/ic034367r" @default.
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