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• W2032961036 abstract "Recent work in the preparation of organically templated metal sulfates under hydrothermal conditions has been extended to include the sulfation of alpha-molybdena through the synthesis of [C(5)H(14)N(2)][(MoO(3))(3)(SO(4))].H(2)O. Single crystals were grown under hydrothermal conditions from molybdenum oxide, water, sulfuric acid, and an enantiomerically pure (R)-2-methylpiperazine source and characterized using both single-crystal X-ray diffraction and infrared spectroscopy. One-dimensional [(MoO(3))(3)(SO(4))](n)(2n-) chains, based on a neutral alpha-molybdena backbone, are connected through an extensive hydrogen-bonding network containing [C(5)H(14)N(2)](2+) cations and occluded water molecules. The direction of the hydrogen bonding is primarily dictated by the nucleophilicity of the respective oxide ligands, as determined using bond valence sums." @default.
• W2032961036 created "2016-06-24" @default.
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• W2032961036 date "2004-09-18" @default.
• W2032961036 modified "2023-09-27" @default.
• W2032961036 title "[C₅H₁₄N₂][(MoO₃)₃(SO₄)]·H₂O: Sulfated α-Molybdena Chains" @default.
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• W2032961036 doi "https://doi.org/10.1021/ic049192f" @default.
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