Matches in SemOpenAlex for { <https://semopenalex.org/work/W2033396726> ?p ?o ?g. }
- W2033396726 endingPage "1059" @default.
- W2033396726 startingPage "1051" @default.
- W2033396726 abstract "Two rate processes characterize the helix-random coil transition in synthetic polypeptides. A slow rate is obtained by an interpretation of separate helix and random coil peaks in the NMR spectra. A faster rate is obtained from relaxation time measurements which utilize rapid reaction techniques. The present model describes the time dependent behavior of polypeptides in the transition region by combining random walk probabilities with conventional equilibrium distributions of conformations. Average conformational lifetimes for each peptide unit were calculated for molecules containing up to 150 units. These results indicate that in the transition region no helical unit is sufficiently long lived to be individually distinguishable by NMR. Spectra are simulated using a two site model for exchanging systems. On the basis of these model calculations the two peaks observed in the NMR spectra are attributed to (1) the all random coil species and (2) all other conformations containing at least one helix unit." @default.
- W2033396726 created "2016-06-24" @default.
- W2033396726 creator A5003773351 @default.
- W2033396726 creator A5023494109 @default.
- W2033396726 creator A5063346260 @default.
- W2033396726 date "1973-01-01" @default.
- W2033396726 modified "2023-09-24" @default.
- W2033396726 title "Polypeptide helix lifetimes in the helix-random coil transition region. Application to NMR spectra" @default.
- W2033396726 cites W1967263522 @default.
- W2033396726 cites W1976097488 @default.
- W2033396726 cites W2008414649 @default.
- W2033396726 cites W2018875546 @default.
- W2033396726 cites W2047623474 @default.
- W2033396726 cites W2076682864 @default.
- W2033396726 cites W2079352045 @default.
- W2033396726 cites W2087580431 @default.
- W2033396726 cites W2089264097 @default.
- W2033396726 cites W2109895318 @default.
- W2033396726 cites W2621258760 @default.
- W2033396726 doi "https://doi.org/10.1002/polc.5070420255" @default.
- W2033396726 hasPublicationYear "1973" @default.
- W2033396726 type Work @default.
- W2033396726 sameAs 2033396726 @default.
- W2033396726 citedByCount "2" @default.
- W2033396726 crossrefType "journal-article" @default.
- W2033396726 hasAuthorship W2033396726A5003773351 @default.
- W2033396726 hasAuthorship W2033396726A5023494109 @default.
- W2033396726 hasAuthorship W2033396726A5063346260 @default.
- W2033396726 hasConcept C105795698 @default.
- W2033396726 hasConcept C121194460 @default.
- W2033396726 hasConcept C121332964 @default.
- W2033396726 hasConcept C1276947 @default.
- W2033396726 hasConcept C133571119 @default.
- W2033396726 hasConcept C15744967 @default.
- W2033396726 hasConcept C159467904 @default.
- W2033396726 hasConcept C178790620 @default.
- W2033396726 hasConcept C185592680 @default.
- W2033396726 hasConcept C18903297 @default.
- W2033396726 hasConcept C2776029896 @default.
- W2033396726 hasConcept C2778530040 @default.
- W2033396726 hasConcept C2779965526 @default.
- W2033396726 hasConcept C30403606 @default.
- W2033396726 hasConcept C32909587 @default.
- W2033396726 hasConcept C33923547 @default.
- W2033396726 hasConcept C34349673 @default.
- W2033396726 hasConcept C46141821 @default.
- W2033396726 hasConcept C4839761 @default.
- W2033396726 hasConcept C62520636 @default.
- W2033396726 hasConcept C66974803 @default.
- W2033396726 hasConcept C67787023 @default.
- W2033396726 hasConcept C71240020 @default.
- W2033396726 hasConcept C77805123 @default.
- W2033396726 hasConcept C8010536 @default.
- W2033396726 hasConcept C86803240 @default.
- W2033396726 hasConceptScore W2033396726C105795698 @default.
- W2033396726 hasConceptScore W2033396726C121194460 @default.
- W2033396726 hasConceptScore W2033396726C121332964 @default.
- W2033396726 hasConceptScore W2033396726C1276947 @default.
- W2033396726 hasConceptScore W2033396726C133571119 @default.
- W2033396726 hasConceptScore W2033396726C15744967 @default.
- W2033396726 hasConceptScore W2033396726C159467904 @default.
- W2033396726 hasConceptScore W2033396726C178790620 @default.
- W2033396726 hasConceptScore W2033396726C185592680 @default.
- W2033396726 hasConceptScore W2033396726C18903297 @default.
- W2033396726 hasConceptScore W2033396726C2776029896 @default.
- W2033396726 hasConceptScore W2033396726C2778530040 @default.
- W2033396726 hasConceptScore W2033396726C2779965526 @default.
- W2033396726 hasConceptScore W2033396726C30403606 @default.
- W2033396726 hasConceptScore W2033396726C32909587 @default.
- W2033396726 hasConceptScore W2033396726C33923547 @default.
- W2033396726 hasConceptScore W2033396726C34349673 @default.
- W2033396726 hasConceptScore W2033396726C46141821 @default.
- W2033396726 hasConceptScore W2033396726C4839761 @default.
- W2033396726 hasConceptScore W2033396726C62520636 @default.
- W2033396726 hasConceptScore W2033396726C66974803 @default.
- W2033396726 hasConceptScore W2033396726C67787023 @default.
- W2033396726 hasConceptScore W2033396726C71240020 @default.
- W2033396726 hasConceptScore W2033396726C77805123 @default.
- W2033396726 hasConceptScore W2033396726C8010536 @default.
- W2033396726 hasConceptScore W2033396726C86803240 @default.
- W2033396726 hasIssue "2" @default.
- W2033396726 hasLocation W20333967261 @default.
- W2033396726 hasOpenAccess W2033396726 @default.
- W2033396726 hasPrimaryLocation W20333967261 @default.
- W2033396726 hasRelatedWork W1968215661 @default.
- W2033396726 hasRelatedWork W1969471102 @default.
- W2033396726 hasRelatedWork W1977919754 @default.
- W2033396726 hasRelatedWork W1991097577 @default.
- W2033396726 hasRelatedWork W2003441475 @default.
- W2033396726 hasRelatedWork W2020271553 @default.
- W2033396726 hasRelatedWork W2027046229 @default.
- W2033396726 hasRelatedWork W2036440189 @default.
- W2033396726 hasRelatedWork W2083380691 @default.
- W2033396726 hasRelatedWork W3008750747 @default.
- W2033396726 hasVolume "42" @default.
- W2033396726 isParatext "false" @default.
- W2033396726 isRetracted "false" @default.
- W2033396726 magId "2033396726" @default.