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• W2034952964 startingPage "5470" @default.
• W2034952964 abstract "The correlation between the fluorescent dynamics of excited anilinonaphthalene sulfonate (ANS) and the microviscosity of solvent molecules surrounding ANS is investigated by time-resolved fluorescence spectroscopy. ANS has been widely used to probe the local hydrophobicity due to the drastic change in its intensity. It is revealed that the fluorescence lifetime from the charge transfer (CT) state of ANS sensitively reflects the microviscosity. The higher sensitivity of 2,6-ANS than of 1,8-ANS demonstrates that the spatial freedom of the rotating phenylamino group in the photoexcited ANS is an important factor that determines the sensitivity. As an application, the measurements of the microviscosity of water in biologically important systems, such as hyaluronan, gellan gum, and gelatin aqueous solutions are also presented. The present results suggest that the fluorescence lifetime of ANS enables the estimation of the solvent microviscosity and provide a useful probe molecule for fluorescence lifetime imaging microscopy." @default.
• W2034952964 created "2016-06-24" @default.
• W2034952964 creator A5051984018 @default.
• W2034952964 creator A5070886067 @default.
• W2034952964 date "2010-06-04" @default.
• W2034952964 modified "2023-10-11" @default.
• W2034952964 title "Fluorescence Lifetime Probe for Solvent Microviscosity Utilizing Anilinonaphthalene Sulfonate" @default.
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• W2034952964 doi "https://doi.org/10.1021/ac100116j" @default.
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