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• W2036262132 abstract "The synthesis of ring-opening metathesis polymerization (ROMP) chain transfer agents (CTA)s bearing methacrylate or epoxide end functionality was accomplished. In the presence of these CTAs, the ROMP of cyclooctadiene (COD) initiated with (PCy3)2Cl2RuCHPh afforded the respective telechelic poly(butenylene)s with either methacrylate or epoxide end groups. Control over the polymer molecular weight was demonstrated by varying the COD/CTA ratio. Successful cross-linking by thermal or photochemical initiation of the bis(methacrylate)-functionalized telechelic poly(butenylene)s or through acid catalysis of the bis(epoxide)-functionalized telechelic poly(butenylene)s was accomplished. While cross-linking was found to reduce solubility of the polymers, it greatly enhanced their thermal stability." @default.
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• W2036262132 date "2000-03-01" @default.
• W2036262132 modified "2023-10-09" @default.
• W2036262132 title "Synthesis of Cross-Linkable Telechelic Poly(butenylene)s Derived from Ring-Opening Metathesis Polymerization" @default.
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• W2036262132 doi "https://doi.org/10.1021/ma9907340" @default.
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