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- W2038656067 abstract "Although PVDF/PMMA blends have been studied extensively, the phase behavior as a function of melt quenching conditions has not been examined in detail in the past. In this paper we report our results on the isotropic blends of PVDF/PMMA quenched into ice water as well as on a casting roll set at 30°C in all composition ranges. The results confirm the miscibility of this blend for all composition ranges, although at high PVDF (∼85%) concentration micro heterogeneities were evidenced through thermal analysis. Though pure PVDF is observed to be mostly in the α crystalline form, the addition of PMMA favors the β crystal structure in composition range 85/15–60/40. Ice water quenching yields amorphous blends containing more than 40% PMMA and these films are deemed good candidates for rubbery state processes (between T g and T cc), including tenter frame biaxial stretching, where they can be oriented significantly at these low temperatures while undergoing strain induced crystallization." @default.
- W2038656067 created "2016-06-24" @default.
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- W2038656067 date "2007-06-01" @default.
- W2038656067 modified "2023-10-09" @default.
- W2038656067 title "Phase Behavior of Rapidly Quenched PVDF/PMMA Blends as Characterized by Raman Spectroscopy, X‐Ray Diffraction and Thermal Techniques" @default.
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- W2038656067 doi "https://doi.org/10.1080/00222340701388680" @default.
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