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• W2040992729 startingPage "369" @default.
• W2040992729 abstract "The preparation and characterization of zinc complexes of formula ZnL2X2 (X = Cl and Br), with L = 1,3-diazinane-2-thione (Diaz), 1,3-diazipane-2-thione (Diap), imidazolidine-2-thione (Imt) and its methyl and n-propyl substituted derivatives, are described. The complexes dichlorobis(1-methylimidazolidine-2-thione-S)-zinc(II) (1) and dichlorobis(1-propylimidazolidine-2-thione-S)-zinc(II) (2) have been characterized by single-crystal X-ray methods. Both complexes adopt distorted tetrahedral geometry. Only intramolecular hydrogen bonding interactions are observed in 1 and 2. Solution and solid state 13C NMR show a significant shift of the C=S carbon resonance of the ligands, while other resonances are relatively unaffected, indicating that most likely the solid state structure is maintained in solution. Antimicrobial activity studies of the free ligands and their complexes show that ligands exhibit substantial antibacterial activities compared to the complexes." @default.
• W2040992729 created "2016-06-24" @default.
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• W2040992729 date "2007-02-20" @default.
• W2040992729 modified "2023-10-03" @default.
• W2040992729 title "Zinc halide complexes of imidazolidine-2-thione and its derivatives: X-ray structures, solid state, solution NMR and antimicrobial activity studies" @default.
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• W2040992729 doi "https://doi.org/10.1080/00958970600780965" @default.
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