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- W2049857885 abstract "Get the bends: The kinetic CH acidity of cyclohex-2-enyl carbamates is dependent on the torsion angle between the α CH bond and the π system of the adjacent double bond. A deprotonation study and DFT calculations of the activation energies for lithiation show that the ease of deprotonation is predictable from a conformational analysis of the substrates. Furthermore, the stereochemical course of substitution reactions was determined. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z603347_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W2049857885 date "2007-02-19" @default.
- W2049857885 modified "2023-10-17" @default.
- W2049857885 title "Estimation of the Kinetic Acidity from Substrate Conformation—Stereochemical Course of the Deprotonation of Cyclohexenyl Carbamates" @default.
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- W2049857885 doi "https://doi.org/10.1002/anie.200603347" @default.
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