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- W2051153204 abstract "Abstract High-yield synthesis (>90%) of two dimeric diphenyl cyclopentadienyl–phenoxyoxochlorotitanium(IV) complexes 3, and 4 has been achieved by hydrolysis of the monomeric 2-(3,4-diphenyl-cyclopentadienyl)-4,6-di-tert-butyl phenoxytitanium dichloride (1) and 2-(3,4-diphenyl-cyclopentadienyl)-6-tert-butyl phenoxytitanium dichloride (2). The molecular structure of 3 has been determined by single-crystal X-ray analysis. Both complexes have been characterized by 1H and 13C NMR spectroscopy. When activated with iBu3Al and Ph 3 C + B ( C 6 F 5 ) 4 - , complexes 3 and 4 exhibit reasonable catalytic activity for ethene polymerization, producing polyethylenes with moderate molecular weights and melting temperatures." @default.
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- W2051153204 date "2005-10-01" @default.
- W2051153204 modified "2023-10-14" @default.
- W2051153204 title "Synthesis, structures, and catalytic properties of dimeric constrained geometry diphenylcyclopentadienyl–phenoxyoxochlorotitanium(IV) complexes" @default.
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- W2051153204 doi "https://doi.org/10.1016/j.poly.2004.09.035" @default.
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