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• W2051249710 abstract "Adipic acid (AA) was crystallized under defined conditions from water containing 0–110 μmol · dm−3 oleic acid (OA). With increasing concentration of OA, the water content of the crystals was constant (0.047 ± 0.005 mole fraction), while the uptake of OA increased linearly, and the dissolution rate (DR) and specific surface area (SSA) of a defined sieve fraction decreased. The decrease in DR exceeded the decrease in SSA. Washing the crystals with chloroform removed an appreciable proportion of the poorly water-soluble OA from the surface of the crystals and produced a marked increase in DR. OA at 15 μmol · dm−3 caused a doubling of DR, whereas higher concentrations reduced DR of the washed crystals to the original value. Increasing incorporation of OA into the AA crystals reduced their density, indicating a decrease in crystallinity. Increasing incorporation of OA also reduced the melting point, Tm, the enthalpy of fusion, ΔHf, and the enthalpy of solution, ΔHs, of the crystals, indicating an increase in energy of the crystalline bulk, corresponding to an increase of lattice strain. Higher concentrations of OA reversed the energetic effects. The reduction in the entropy of fusion by small amounts of OA was greater than the increase in the sum of the ideal partial molar entropies of the components of the crystals by a factor approaching 1000. This indicates that OA greatly disrupts the order of the crystal lattice of AA." @default.
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• W2051249710 date "1985-06-01" @default.
• W2051249710 modified "2023-09-27" @default.
• W2051249710 title "Modification of adipic acid crystals. II. Influence of growth in the presence of oleic acid on crystal properties" @default.
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• W2051249710 doi "https://doi.org/10.1016/0378-5173(85)90103-6" @default.
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