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- W2052595384 abstract "A 3-silolene derivative, 2,2,5,5-tetrakis(dimethylsilyl)-1,1-dimethyl-3,4-diphenyl-3-silolene (TDMSHS), is first synthesized and characterized by X-ray diffraction crystallography and spectroscopic methods. Hydrosilylation polymerization of TDMSHS with 1,1-dimethyl-2,5-bis(4-ethynylphenyl)-3,4-diphenylsilole in the presence of Karstedt's catalyst generates a stereoregular silole-containing hyperbranched poly(silylenevinylene) (hb-SPSV) with a high molecular weight (M(w) = 146,000, M(w)/M(n) = 1.5) in high yield (≈95%). hb-SPSV exhibits excellent thermal stability and strong fluorescence, and the emission of its aggregates in aqueous mixture can be quenched efficiently by picric acid with large quenching constants K(SV) up to 414400 M(-1)." @default.
- W2052595384 created "2016-06-24" @default.
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- W2052595384 date "2012-03-19" @default.
- W2052595384 modified "2023-10-03" @default.
- W2052595384 title "A Fully Substituted 3-Silolene Functions as Promising Building Block for Hyperbranched Poly(Silylenevinylene)" @default.
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- W2052595384 doi "https://doi.org/10.1002/marc.201200085" @default.
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