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• W2064103615 startingPage "213" @default.
• W2064103615 abstract "When the products of the interaction between methanol and either excited argon atoms or F atoms, produced in a discharge, are frozen in a large excess of argon at 14 K, prominent infrared absorptions of CH2OH appear. Detailed isotopic substitution studies have permitted the derivation of a set of valence-force potential constants for this species. There is some evidence for the stabilization of CH3O, previously identified as a product of these two reactions, but the reaction channel producing CH2OH predominates. Secondary H-atom abstraction and photodecomposition lead to the stabilization of H2CO, with no evidence for an HCOH intermediate. HCO also appears. The highest frequency fundamental of DCO stabilized in solid argon agrees considerably more closely with the recently reported gas-phase band center than does the corresponding absorption in a carbon monoxide matrix. In the F-atom reaction studies the [CH2OH+HF] hydrogen-bonded complex is also stabilized. The infrared absorption spectrum of this complex suggests that the HF is hydrogen-bonded to the lone pair electrons on the oxygen atom." @default.
• W2064103615 created "2016-06-24" @default.
• W2064103615 creator A5052620259 @default.
• W2064103615 date "1981-07-01" @default.
• W2064103615 modified "2023-09-27" @default.
• W2064103615 title "The reaction of excited argon atoms and of F atoms with Methanol. Vibrational spectrum of CH2OH isolated in solid argon" @default.
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• W2064103615 doi "https://doi.org/10.1016/0301-0104(81)80101-2" @default.
• W2064103615 hasPublicationYear "1981" @default.
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