FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2065666992> ?p ?o ?g. }

• W2065666992 endingPage "1560" @default.
• W2065666992 startingPage "1554" @default.
• W2065666992 abstract "The gas-phase reaction of ozone with alkenes is known to be a dark source of HOx radicals (such as OH, H, and R) in the troposphere, though the reaction mechanism is currently under debate. It is understood that a key intermediate in the reaction is the carbonyl oxide, which is formed with an excess of vibrational energy. The branching ratios of the ozone−alkene reaction products (and thus HOx yields) depend critically on the fate of this intermediate: it may undergo unimolecular reaction (forming either OH or dioxirane) or be collisionally stabilized by the bath gas. To investigate this competition between reaction and quenching, we present direct, pressure-dependent measurements of hydroxyl radical (OH) yields for a number of gas-phase ozone−alkene reactions. Experiments are carried out in a high-pressure flow system (HPFS) equipped to detect OH using laser-induced fluorescence (LIF). Hydroxyl radicals are measured in steady state, formed from the ozone−alkene reaction and lost to reaction with the alkene. Short reaction times (usually ∼10 ms) ensure negligible interference from secondary and heterogeneous reactions. For all substituted alkenes covered in this study, low-pressure yields are large but decrease rapidly with pressure, resulting in yields at 1 atm which are significantly lower than current recommendations and indicating the important role of collisional stabilization in determining OH yield. The influence of alkene size and degree of substitution on pressure-dependent yield is consistent with the influence of collisional stabilization as well as the accepted reaction mechanism." @default.
• W2065666992 created "2016-06-24" @default.
• W2065666992 creator A5002561581 @default.
• W2065666992 creator A5002729456 @default.
• W2065666992 creator A5006806891 @default.
• W2065666992 creator A5041685684 @default.
• W2065666992 creator A5078338783 @default.
• W2065666992 date "2000-12-05" @default.
• W2065666992 modified "2023-10-14" @default.
• W2065666992 title "Mechanism of HO<i>_x</i> Formation in the Gas-Phase Ozone−Alkene Reaction. 1. Direct, Pressure-Dependent Measurements of Prompt OH Yields" @default.
• W2065666992 cites W1965859078 @default.
• W2065666992 cites W1971457659 @default.
• W2065666992 cites W1986417862 @default.
• W2065666992 cites W1988811044 @default.
• W2065666992 cites W2006154853 @default.
• W2065666992 cites W2006918997 @default.
• W2065666992 cites W2009256533 @default.
• W2065666992 cites W2012510947 @default.
• W2065666992 cites W2030619531 @default.
• W2065666992 cites W2031094612 @default.
• W2065666992 cites W2044671256 @default.
• W2065666992 cites W2046901677 @default.
• W2065666992 cites W2053797675 @default.
• W2065666992 cites W2055385225 @default.
• W2065666992 cites W2063511039 @default.
• W2065666992 cites W2065406967 @default.
• W2065666992 cites W2073410237 @default.
• W2065666992 cites W2075256441 @default.
• W2065666992 cites W2084034186 @default.
• W2065666992 cites W2084865382 @default.
• W2065666992 cites W2089481164 @default.
• W2065666992 cites W2089758115 @default.
• W2065666992 cites W2093659080 @default.
• W2065666992 cites W2102997157 @default.
• W2065666992 cites W2152814694 @default.
• W2065666992 cites W320211004 @default.
• W2065666992 doi "https://doi.org/10.1021/jp002121r" @default.
• W2065666992 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34500545" @default.
• W2065666992 hasPublicationYear "2000" @default.
• W2065666992 type Work @default.
• W2065666992 sameAs 2065666992 @default.
• W2065666992 citedByCount "164" @default.
• W2065666992 countsByYear W20656669922012 @default.
• W2065666992 countsByYear W20656669922013 @default.
• W2065666992 countsByYear W20656669922014 @default.
• W2065666992 countsByYear W20656669922015 @default.
• W2065666992 countsByYear W20656669922016 @default.
• W2065666992 countsByYear W20656669922017 @default.
• W2065666992 countsByYear W20656669922018 @default.
• W2065666992 countsByYear W20656669922019 @default.
• W2065666992 countsByYear W20656669922020 @default.
• W2065666992 countsByYear W20656669922021 @default.
• W2065666992 countsByYear W20656669922022 @default.
• W2065666992 countsByYear W20656669922023 @default.
• W2065666992 crossrefType "journal-article" @default.
• W2065666992 hasAuthorship W2065666992A5002561581 @default.
• W2065666992 hasAuthorship W2065666992A5002729456 @default.
• W2065666992 hasAuthorship W2065666992A5006806891 @default.
• W2065666992 hasAuthorship W2065666992A5041685684 @default.
• W2065666992 hasAuthorship W2065666992A5078338783 @default.
• W2065666992 hasConcept C121332964 @default.
• W2065666992 hasConcept C134121241 @default.
• W2065666992 hasConcept C139066938 @default.
• W2065666992 hasConcept C161790260 @default.
• W2065666992 hasConcept C178790620 @default.
• W2065666992 hasConcept C185592680 @default.
• W2065666992 hasConcept C2776130953 @default.
• W2065666992 hasConcept C2776254738 @default.
• W2065666992 hasConcept C508106653 @default.
• W2065666992 hasConcept C65024703 @default.
• W2065666992 hasConcept C75473681 @default.
• W2065666992 hasConcept C97355855 @default.
• W2065666992 hasConceptScore W2065666992C121332964 @default.
• W2065666992 hasConceptScore W2065666992C134121241 @default.
• W2065666992 hasConceptScore W2065666992C139066938 @default.
• W2065666992 hasConceptScore W2065666992C161790260 @default.
• W2065666992 hasConceptScore W2065666992C178790620 @default.
• W2065666992 hasConceptScore W2065666992C185592680 @default.
• W2065666992 hasConceptScore W2065666992C2776130953 @default.
• W2065666992 hasConceptScore W2065666992C2776254738 @default.
• W2065666992 hasConceptScore W2065666992C508106653 @default.
• W2065666992 hasConceptScore W2065666992C65024703 @default.
• W2065666992 hasConceptScore W2065666992C75473681 @default.
• W2065666992 hasConceptScore W2065666992C97355855 @default.
• W2065666992 hasIssue "9" @default.
• W2065666992 hasLocation W20656669921 @default.
• W2065666992 hasOpenAccess W2065666992 @default.
• W2065666992 hasPrimaryLocation W20656669921 @default.
• W2065666992 hasRelatedWork W1977808892 @default.
• W2065666992 hasRelatedWork W2042409214 @default.
• W2065666992 hasRelatedWork W2080217121 @default.
• W2065666992 hasRelatedWork W2129449874 @default.
• W2065666992 hasRelatedWork W2159791565 @default.
• W2065666992 hasRelatedWork W2294048369 @default.
• W2065666992 hasRelatedWork W2323695351 @default.
• W2065666992 hasRelatedWork W3119593865 @default.
• W2065666992 hasRelatedWork W3214006403 @default.
• W2065666992 hasRelatedWork W4233165202 @default.

• next