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• W2069860520 startingPage "25671" @default.
• W2069860520 abstract "The effect of thiol and selenol functionalization on the vibrational spectra and photochemical stability of terthiophene based molecular wires was investigated using surface-enhanced Raman scattering (SERS). The molecules were found to exhibit markedly different properties at the silver surface of the SERS substrate, despite having almost identical Raman spectra in solution and in the solid state. In contrast to terthiophene (3T), the bisthiolterthiophene (T3) and biselenol-terthiophene (Se3) molecules were stable against photoinduced structural changes when adsorbed to the metal surface at low concentrations. This indicates that the strong bonds to the silver surface, via S or Se terminal atoms, leads to a rapid decay of photoexcited states. Comparison with ab initio calculations shows that both T3 and Se3 bind with only one of the functional groups to the Ag surface." @default.
• W2069860520 created "2016-06-24" @default.
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• W2069860520 date "2006-12-01" @default.
• W2069860520 modified "2023-09-27" @default.
• W2069860520 title "Raman Spectroscopic Studies of Terthiophenes for Molecular Electronics" @default.
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• W2069860520 doi "https://doi.org/10.1021/jp062577u" @default.
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