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- W2081798889 abstract "The transition state for the hydronium-ion-promoted hydrolysis of α-d-glucopyranosyl fluoride in water has been characterized by combining multiple kinetic isotope effect measurements with theoretical modelling. The measured kinetic isotope effects for the C1-deuterium, C2-deuterium, C5-deuterium, anomeric carbon-13, and ring oxygen-18 are 1.219 ± 0.021, 1.099 ± 0.024, 0.976 ± 0.014, 1.014 ± 0.005, and 0.991 ± 0.013, respectively. The transition state for the hydronium ion reaction is late with respect to both C–F bond cleavage and proton transfer." @default.
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- W2081798889 date "2015-04-01" @default.
- W2081798889 modified "2023-10-16" @default.
- W2081798889 title "Transition-state structure for the hydronium-ion-promoted hydrolysis of α-<scp>d</scp>-glucopyranosyl fluoride" @default.
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- W2081798889 doi "https://doi.org/10.1139/cjc-2014-0451" @default.
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