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- W2082202562 abstract "Publisher Summary This chapter reviews the synthetic and structural chemistry of molecular alumo-siloxanes, which combine in a molecular entity the elements aluminum and silicon connected by oxygen. They may be regarded as molecular counterparts of alumo-silicates, which have attracted considerable attention owing to their solid-state cage structures. The chapter focuses on alumo-poly siloxanes that may be derived from a poly siloxane of the general formula (R 2 SiO) n by replacing several R 2 SiO units by AlOX with X=OH, in most cases, and their base derivatives. The chapter highlights some general structural details of compounds of the general formula (R x SiO y ) n (AlOX) m . It concentrates on the hydroxy compounds and their base adducts, and neglects most of the results in the area of molecular alumo-silicates in which the protons are substituted by metallic elements. The adducts of the polycyclic compound (Ph 2 SiO) 8 [A1O(OH)] 4 with different bases show that this molecular amino-siloxane can be easily used for supramolecular assemblies." @default.
- W2082202562 created "2016-06-24" @default.
- W2082202562 creator A5015761442 @default.
- W2082202562 date "2006-01-01" @default.
- W2082202562 modified "2023-10-18" @default.
- W2082202562 title "Molecular Alumo-Siloxanes and Base Adducts" @default.
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- W2082202562 doi "https://doi.org/10.1016/s0065-3055(05)54002-4" @default.
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