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• W2083943670 abstract "Hexakis(tert-butyldimethylsilyl)bicyclo[1.1.0]tetrasilane (3), which is known to isomerize to the corresponding cyclotetrasilene 4 above 0 °C, was synthesized via an alternative synthetic route and isolated at low temperatures as air-sensitive yellow crystals. The short-bond structure of 3 was disclosed by X-ray analysis and DFT calculations, and facile ring flipping of 3 below 0 °C with the activation parameters of ΔH‡ = 6.67 ± 0.18 kcal mol−1 and ΔS‡ = −22.7 ± 0.8 cal mol−1 K−1 was observed." @default.
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• W2083943670 date "2008-01-10" @default.
• W2083943670 modified "2023-09-30" @default.
• W2083943670 title "Synthesis, Structure, and Facile Ring Flipping of a Bicyclo[1.1.0]tetrasilane" @default.
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• W2083943670 doi "https://doi.org/10.1021/om7011375" @default.
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