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- W2085804810 abstract "Bazzanin S, a new chlorinated bisbibenzyl of the isoplagiochin D type, as well as isoplagiochin D itself were isolated from the liverwort Bazzania trilobata. The structure of bazzanin S was elucidated based on extensive NMR spectral evidence and by mass spectrometry. Both macrocyclic compounds, bazzanin S and isoplagiochin D, as well as previously reported bazzanins exhibit optical activity, but are not enantiopure in nature. The enantiomeric ratios of a broad array of different cyclic bisbibenzyls, isoplagiochin D, bazzanins A–C and F–J, and bazzanin S, were determined by HPLC on a chiral phase. Exemplarily for the halogen-free parent compound isoplagiochin D, elucidation of the absolute configuration was achieved by quantum chemical CD calculations." @default.
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- W2085804810 date "2004-10-01" @default.
- W2085804810 modified "2023-10-15" @default.
- W2085804810 title "Optically active bisbibenzyls from Bazzania trilobata: isolation and stereochemical analysis by chromatographic, chiroptical, and computational methods" @default.
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- W2085804810 doi "https://doi.org/10.1016/j.tet.2004.08.037" @default.
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