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• W2093118889 abstract "The reaction of [RuCp(CH3CN)3]PF6 (1) with the monodentate ligands PR3 (R = Me, Ph, Cy) affords the cationic complexes [RuCp(PR3)(CH3CN)2]PF6 (2a−c) in high yields. The CH3CN exchange kinetics has been studied by NMR, suggesting a dissociative mechanism. Due to van der Waals repulsive interactions between PCy3 and the nitrile ligands, CH3CN is particularly labile in 2c. The chemistry of 2a−c has been further investigated with respect to substitution and oxidative addition." @default.
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• W2093118889 date "1999-09-01" @default.
• W2093118889 modified "2023-09-23" @default.
• W2093118889 title "[RuCp(PR₃)(CH₃CN)₂]PF₆ (R = Ph, Me, Cy). Convenient Precursors for Mixed Ruthenium(II) and Ruthenium(IV) Half-Sandwich Complexes" @default.
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• W2093118889 doi "https://doi.org/10.1021/om990245o" @default.
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