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• W2095021940 abstract "The coordination chemistry of 1,1'-diisocyanoferrocene (1) was investigated. Its reaction with Cr(CO)5(THF) (2 equiv) affords (1)[Cr(CO)5]2, which exhibits eclipsed cyclopentadienyl rings with a synclinal arrangement of the two substituents. 1 behaves like an aryl isocyanide in this compound according to IR spectroscopic data, and its oxidation leads to a marked decrease of net electron donor ability. The reaction of 1 with AuCl(SMe2) affords the insoluble coordination polymer [(1)(AuCl)2]infinity. The (1)(AuCl)2 molecules adopt a 3,4-diaura-[6]ferrocenophane structure. They are aggregated in a zipperlike fashion through aurophilic interactions, with Au-Au distances ranging from 3.34 to 3.48 A. The adsorption of 1 from acetonitrile solution on polycrystalline gold affords a self-assembled monolayer. Both isocyanide groups are binding to the surface." @default.
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• W2095021940 date "2005-01-06" @default.
• W2095021940 modified "2023-09-25" @default.
• W2095021940 title "The Interaction of 1,1‘-Diisocyanoferrocene with Gold: Formation of Monolayers and Supramolecular Polymerization of an Aurophilic Ferrocenophane" @default.
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• W2095021940 doi "https://doi.org/10.1021/ja0436244" @default.
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