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• W2109697072 abstract "Summary: Diblock copolymers (DBCs) of MOPEO-b-PCL containing biocompatibleand biodegradable components: hydrophilic methoxypoly-(ethylene oxide)(M n ¼2.5kDa¼const) and hydrophobic poly(e-caprolactone) of a variable chainlength (M n ¼2.8 24.3kDa) were synthesized by an anionic ring-opening blockcopolymerization. Their chemical and microphase structure were characterized usingFTIR,NMR,DSCandWAXS.Self-assemblyofpureDBCsandthoseatthepresenceofamodel drug prednisolon (PS) in dioxane/aqueous solutions was studied using visiblespectroscopyandstaticlightscattering.Increasinginthemicellar stabilityatthePCLblock lengthening and PS addition was revealed. The drug binding by DBC micellesdue to hydrogen bonds and hydrophobic interactions was confirmed by FTIR. Keywords: block copolymers; micelles; prednisolon; self-assembly; structure Introduction In recent years, the solution of a problem,concerned with effective drug delivery usingnanoscaled carriers,receive specialattentionnotonlyinmedicine,butalsoinbiochemistryand polymeric science. Treatment of tuber-culosis, inflammatory diseases and, espe-cially, cancer need new strategies, which canimprove the efficacy and security of thetherapy. Various drug carriers, such as solidlipid nanoparticles, macromolecular pro-drugs, nanoparticles made of biodegradablenatural and synthetic polymers, microcap-sules, liposomes, naturally existing proteins(e.g. transferrin) and polymer micelles arecurrently under development." @default.
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• W2109697072 date "2012-08-01" @default.
• W2109697072 modified "2023-09-27" @default.
• W2109697072 title "Micellization and Structure of MOPEO-b -PCL Copolymers and Their Application as Nanocontainers for Drugs" @default.
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• W2109697072 doi "https://doi.org/10.1002/masy.201100069" @default.
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